Coated article and method for making the same

ABSTRACT

A coated article includes a substrate, an anti-corrosion layer formed on the substrate, and a decorative layer formed on the anti-corrosion layer. The substrate is made of magnesium or magnesium alloy. The anti-corrosion layer includes a magnesium layer formed on the substrate and a magnesium oxynitride layer formed on the magnesium layer. The coated article has improved corrosion resistance.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application is one of the eleven related co-pending U.S. patent applications listed below. All listed applications have the same assignee. The disclosure of each of the listed applications is incorporated by reference into all the other listed applications.

Attorney Docket No. Title Inventors US 34965 COATED ARTICLE AND METHOD HSIN-PEI FOR MAKING THE SAME CHANG et al. US 34966 COATED ARTICLE AND METHOD HSIN-PEI FOR MAKING THE SAME CHANG et al. US 34967 COATED ARTICLE AND METHOD HSIN-PEI FOR MAKING THE SAME CHANG et al. US 34969 COATED ARTICLE AND METHOD HSIN-PEI FOR MAKING THE SAME CHANG et al. US 36035 COATED ARTICLE AND METHOD HSIN-PEI FOR MAKING THE SAME CHANG et al. US 36036 COATED ARTICLE AND METHOD HSIN-PEI FOR MAKING THE SAME CHANG et al. US 36037 COATED ARTICLE AND METHOD HSIN-PEI FOR MAKING THE SAME CHANG et al. US 36038 COATED ARTICLE AND METHOD HSIN-PEI FOR MAKING THE SAME CHANG et al. US 36039 COATED ARTICLE AND METHOD HSIN-PEI FOR MAKING THE SAME CHANG et al. US 36040 COATED ARTICLE AND METHOD HSIN-PEI FOR MAKING THE SAME CHANG et al. US 36041 COATED ARTICLE AND METHOD HSIN-PEI FOR MAKING THE SAME CHANG et al.

BACKGROUND

1. Technical Field

The present disclosure relates to coated articles and a method for making the coated articles.

2. Description of Related Art

Physical vapor deposition (PVD) is an environmentally friendly coating technology. Coating metal substrates using PVD is widely applied in various industrial fields.

The standard electrode potential of magnesium or magnesium alloy is very low. Thus, the magnesium or magnesium alloy substrates may often suffer galvanic corrosion. When the magnesium or magnesium alloy substrate is coated with a decorative layer such as a titanium nitride (TiN) or chromium nitride (CrN) layer using PVD, the potential difference between the decorative layer and the substrate is high and the decorative layer made by PVD will often have small openings such as pinholes and cracks, which can accelerate galvanic corrosion of the substrate.

Therefore, there is room for improvement within the art.

BRIEF DESCRIPTION OF THE FIGURE

Many aspects of the coated article and the method for making the coated article can be better understood with reference to the following drawings. The components in the drawings are not necessarily drawn to scale, the emphasis instead being placed upon clearly illustrating the principles of the coated article and the method. Moreover, in the drawings like reference numerals designate corresponding parts throughout the several views. Wherever possible, the same reference numbers are used throughout the drawings to refer to the same or like elements of an embodiment.

FIG. 1 is a cross-sectional view of an exemplary coated article;

FIG. 2 is a schematic view of a vacuum sputtering device for fabricating the coated article in FIG. 1.

DETAILED DESCRIPTION

FIG. 1 shows a coated article 10 according to an exemplary embodiment. The coated article 10 includes a substrate 11, an anti-corrosion layer 13 formed on the substrate 11, and a decorative layer 15 formed on the anti-corrosion layer 13. The coated article 10 may be used as a housing for a computer, a communication device, or a consumer electronic device.

The substrate 11 is made of magnesium or magnesium alloy.

The anti-corrosion layer 13 includes a magnesium layer 131 formed on the substrate 11 and a magnesium oxynitride (MgON) layer 133 formed on the magnesium layer 131. The magnesium layer 131 has a thickness of about 0.2 μm to about 0.5 μm. The magnesium oxynitride layer 133 has a thickness of about 0.5 μm to about 1.0 μm.

The decorative layer 17 may be a titanium nitride (TiN) or chromium nitride (CrN) layer. The decorative layer 17 has a thickness of about 1.0 μm to about 3.0 μm. A vacuum sputtering process may be used to form the anti-corrosion layer 13 and the decorative layer 15.

FIG. 2 shows a vacuum sputtering device 20, which includes a vacuum chamber 21 and a vacuum pump 30 connected to the vacuum chamber 21. The vacuum pump 30 is used for evacuating the vacuum chamber 21. The vacuum chamber 21 has magnesium targets 23, titanium or chromium targets 24 and a rotary rack (not shown) positioned therein. The rotary rack holding the substrate 11 revolves along a circular path 25, and the substrate 11 is also revolved about its own axis while being carried by the rotary rack.

A method for making the coated article 10 may include the following steps:

The substrate 11 is pretreated. The pre-treating process may include the following steps: electrolytic polishing the substrate 11; wiping the surface of the substrate 11 with deionized water and alcohol; ultrasonically cleaning the substrate 11 with acetone solution in an ultrasonic cleaner (not shown), to remove impurities such as grease or dirt from the substrate 11. Then, the substrate 11 is dried.

The substrate 11 is positioned in the rotary rack of the vacuum chamber 21 to be plasma cleaned. The vacuum chamber 21 is then evacuated to 1.0×10⁻³ Pa. Argon gas (abbreviated as Ar, having a purity of about 99.999%) is used as the sputtering gas and is fed into the vacuum chamber 21 at a flow rate of about 250 standard-state cubic centimeters per minute (sccm) to about 500 sccm. A negative bias voltage in a range from about −300 volts (V) to about −800 V is applied to the substrate 11. The plasma then strikes the surface of the substrate 11 to clean the surface of the substrate 11. The plasma cleaning of the substrate 11 takes about 3 minutes (min) to about 10 min. The plasma cleaning process enhances the bond between the substrate 11 and the anti-corrosion layer 13.

The magnesium layer 131 is vacuum sputtered on the plasma cleaned substrate 11. Vacuum sputtering of the magnesium layer 131 is carried out in the vacuum chamber 21. The vacuum chamber 21 is heated to a temperature of about 80° C. to about 120° C. Ar is used as the sputtering gas and is fed into the vacuum chamber 21 at a flow rate of about 100 sccm to about 300 sccm. The magnesium targets 23 are supplied with electrical power of about 5 kw to about 8 kw. A negative bias voltage of about −50 V to about −100 V is applied to the substrate 11 and the duty cycle is from about 50% to about 80%. Deposition of the magnesium layer 131 takes about 20 min to about 40 min.

The MgON layer 133 is vacuum sputtered on the magnesium layer 131. Vacuum sputtering of the MgON layer 133 is carried out in the vacuum chamber 21. Oxygen (O₂) is used as the reaction gas and is fed into the vacuum chamber 21 at a flow rate of about 50 sccm to about 100 sccm. Nitrogen (N₂) is used as the reaction gas and is fed into the vacuum chamber 21 at a flow rate of about 30 sccm to about 100 sccm. Other conditions are substantially the same as vacuum sputtering of the magnesium layer 131. Deposition of the MgON layer 133 takes about 40 min to about 90 min.

The decorative layer 15 is vacuum sputtered on the anti-corrosion layer 13. Vacuum sputtering of the decorative layer 17 is carried out in the vacuum chamber 21. Nitrogen (N₂) is used as the reaction gas and is fed into the vacuum chamber 21 at a flow rate of about 20 sccm to about 200 sccm. Magnesium targets 23 are powered off and titanium or chromium targets 24 are supplied with electrical power of about 5 kw to about 10 kw. Other conditions are substantially the same as vacuum sputtering of the magnesium layer 131. Deposition of the decorative layer 15 takes about 20 min to about 40 min. The decorative layer 15 is a TiN or CrN layer.

When the coated article 10 is in a corrosive environment, the anti-corrosion layer 13 can slow down galvanic corrosion of the substrate 11 due to the low potential difference between the anti-corrosion layer 13 and the substrate 11. Additionally, the MgON layer 15 has dense structure, which can effectively slow penetration of the outside corrosive mediums towards the substrate 11. Thus, the corrosion resistance of the coated article 10 is improved. The decorative layer 15 has stable properties and gives the coated article 10 a long lasting pleasing appearance.

It is believed that the exemplary embodiment and its advantages will be understood from the foregoing description, and it will be apparent that various changes may be made thereto without departing from the spirit and scope of the disclosure or sacrificing all of its advantages, the examples hereinbefore described merely being preferred or exemplary embodiment of the disclosure. 

1. A coated article, comprising: a substrate, the substrate being made of magnesium or magnesium alloy; and an anti-corrosion layer formed on the substrate, the anti-corrosion layer including a magnesium layer formed on the substrate and a magnesium oxynitride layer formed on the magnesium layer.
 2. The coated article as claimed in claim 1, wherein the coated article further comprises a decorative layer formed on the anti-corrosion layer.
 3. The coated article as claimed in claim 2, wherein the decorative layer is a titanium nitride layer.
 4. The coated article as claimed in claim 2, wherein the decorative layer is a chromium nitride layer.
 5. The coated article as claimed in claim 2, wherein the decorative layer has a thickness of about 1.0 μm to about 3.0 μm.
 6. The coated article as claimed in claim 1, wherein the magnesium layer has a thickness of about 0.2 μm to about 0.5 μm.
 7. The coated article as claimed in claim 1, wherein the magnesium oxynitride layer has a thickness of about 0.5 μm to about 1.0 μm.
 8. A method for making a coated article, comprising: providing a substrate, the substrate being made of magnesium or magnesium alloy; magnetron sputtering a anti-corrosion layer on the substrate, the anti-corrosion layer including a magnesium layer formed on the substrate and a magnesium oxynitride layer formed on the magnesium layer.
 9. The method as claimed in claim 8, wherein magnetron sputtering the magnesium layer uses argon gas as the sputtering gas and the argon gas has a flow rate of about 100 sccm to about 300 sccm; magnetron sputtering the magnesium layer is carried out at a temperature of about 80° C. to about 120° C.; uses magnesium targets and the magnesium targets are supplied with a power of about 5 kw to about 8 kw; a negative bias voltage of about −50 V to about −100 V is applied to the substrate and the duty cycle is from about 50% to about 80%.
 10. The method as claimed in claim 9, wherein magnetron sputtering the magnesium layer takes about 20 min to about 40 min.
 11. The method as claimed in claim 8, wherein magnetron sputtering the magnesium oxynitride layer uses nitrogen and oxygen as the reaction gas, the nitrogen has a flow rate of about 30 sccm to about 100 sccm, the oxygen has a flow rate of about 50 sccm to about 100 sccm; uses argon gas as the sputtering gas and the argon gas has a flow rate of about 100 sccm to about 300 sccm; magnetron sputtering the magnesium oxynitride layer is carried out at a temperature of about 80° C. to about 120° C.; uses magnesium targets and the magnesium targets are supplied with a power of about 5 kw to about 8 kw; a negative bias voltage of about −50 V to about −100 V is applied to the substrate and the duty cycle is from about 50% to about 80%.
 12. The method as claimed in claim 11, wherein magnetron sputtering the magnesium oxynitride layer takes about 40 min to about 90 min.
 13. The method as claimed in claim 8, wherein the method further comprises magnetron sputtering a decorative layer on the anti-corrosion layer.
 14. The method as claimed in claim 13, wherein magnetron sputtering the decorative layer uses nitrogen as the reaction gas and nitrogen has a flow rate of about 20 sccm to about 200 sccm; argon gas as the sputtering gas and argon gas has a flow rate of about 100 sccm to about 300 sccm; magnetron sputtering the decorative layer is carried out at a temperature of about 80° C. to about 120° C.; uses titanium or chromium targets and the titanium or chromium targets are supplied with a power of about 5 kw to about 10 kw; a negative bias voltage of about −50 V to about −100 V is applied to the substrate and the duty cycle is from about 50% to about 80%.
 15. The method as claimed in claim 14, wherein vacuum sputtering the decorative layer takes about 20 min to about 40 min. 